Calculation of phase equilibria in Al-Fe-Mn ternary system involving three new ternary intermetallic compounds

doi:10.1007/s40436-017-0199-0

Abstract

Abstract: In this study, the Al-Fe-Mn ternary system is reassessed by the CALPHAD method. Three new ternary intermetallic compounds are initially described and a reasonable and self-consistent set of thermodynamic parameters are established to describe this system. The 973 K, 1 073 K, 1 173 K, 1 273 K, 1 373 K, and 1 473 K isothermal sections and the 1 073 K, 1 013 K, 968 K and 913 K isothermal sections at the Al corner as well as the liquidus projection at the Al corner are calculated. It is shown that the calculated results are in good agreement with almost all of the experimental results previously reported.

The full text can be downloaded at https://link.springer.com/article/10.1007/s40436-017-0199-0

Key words: Al-Fe-Mn, CALPHAD, Phase equilibria, Isothermal sections

Lu-Hai Zhou, Zhu Li, Shu-Sen Wang, Ren-Min Hu, Shi-Hua Wang, Zi-Wei Qin, Xiong-Gang Lu, Chong-He Li. Calculation of phase equilibria in Al-Fe-Mn ternary system involving three new ternary intermetallic compounds[J]. Advances in Manufacturing, 2018, 6(2): 247-257.

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References

1. Hadfield R (1988) Hadfield's manganese steel. Science 12(306):284-286
2. Frommeyer G, Drewes EJ, Engl B (2000) Physical and mechanical properties of iron-aluminum-(Mn, Si) light weight steels. Rev Met Paris 97(10):1245-1253
3. Bouaziz O, Allain S, Scott CP et al (2011) High manganese austenitic twinning induced plasticity steels:a review of the microstructure properties relationships. Curr Opin Solid State Mater Sci 15(4):141-168
4. Koester W, Tonn W (1933) The iron corner of the iron-manganese-aluminum system. Arch Eisenhuettenwes 7:365-366
5. Degischer E (1939) The aluminum corner of the ternary system aluminum-iron-manganese. Alum Arch 18:5-19
6. Phi Phillips HWL, Varley PC (1943) The constitution of alloys of aluminum with manganese, ailicon and iron. J Inst Met 69:275-316
7. Muravyova AA, Zarechnyuk OS, Ryabovv R (1974) Investigation of the manganese-iron-aluminum system. Vestn L'vov Univ Khim 16:3-4
8. Shvedov LI, Goretskii GP (1974) Structure of Fe-Mn-Al alloys. Minsk, Izdatel'stvo Nauka i Tekhnika, Russian
9. Chakrabarti DJ (1977) Phase stability in ternary systems of transition elements with aluminum. Metall Trans B 8B:121-123
10. Branco JRT, Boratto FJM (1981) The austenite phase field in the Fe-Mn-Al system at 1 000℃. 36th annual congress of ABM, Recife, Mexico, pp 175-185
11. Denholm WT, Esdaile JD, Siviour NG et al (1984) Crystallization studies in the aluminum-rich corner of the aluminum-iron-manganese system. Metall Trans A 15A:1311-1317
12. Liu X, Sun R, Hao S (1990) Study of phase equilibria at 1 000℃, 1 100℃ and 1 200℃ in the system Fe-Mn-Al. In:Proceedings of 6th national symposium on phase diagrams, Shenyang, China, pp 146-149
13. Xu L, Guo Y, Liang G et al (1990) Experimental investigation of the equilibrium diagram of Fe corner in Fe-Mn-Al system. In:Proceedings of 6th national symposium on phase diagrams, Shenyang, China, pp 160-162
14. Xu L, Guo Y, Liang G et al (1992) Determination of the phase diagram of Fe-Mn-Al by means of EPMA. Chin J Mater Res 6(3):185-189
15. Hao S, Chen H, Liu X (1993) Study of transverse section of 4wt.% Al and 8wt.% Al in Fe-Mn-Al system phase diagram. J Northeast Univ Technol 14(2):150-154
16. Liu X, Shiming H (1993) Phase equilibria and a (bcc) phase region continuity at 1 000℃ in the Fe-Mn-Al system. Scr Metall Mater 28(5):611-616
17. Liu X, Chen H, Hao S (1993) Phase equilibria of the Fe-Mn-Al system at 1 200℃ and 1 300℃. J Northeast Univ Technol 14(3):249-252
18. Mueller C, Stadelmaier HH, Reinsch B et al (1997) Constitution of Mn-Al-(Cu, Fe, Ni or C) alloys near the magnetic τ phase. Z Metallkd 88(8):620-624
19. Liu X, Hao SA (1993) Thermodynamic calculation of the Fe-MnAl ternary system. Calphad 17(1):79-91
20. Umino R, Liu XJ, Sutou Y et al (2006) Experimental determination and thermodynamic calculation of phase equilibria in the Fe-Mn-Al system. J Phase Equilib Diff 27(1):54-62
21. Lindahl BB, Selleby M (2013) The Al-Fe-Mn system revisited-an updated thermodynamic description using the most recent binaries. Calphad 43:86-93
22. Balanetskyy S, Pavlyuchkov D, Velikanova T (2015) The Al-rich region of the Al-Fe-Mn alloy system. J Alloys Compd 619:211-220
23. Sundman B, Ohnuma I, Dupin N et al (2009) An assessment of the entire Al-Fe system including D0₃ ordering. Acta Mater 57(10):2896-2908
24. Du Y, Wang J, Zhao J (2007) Reassessment of the Al-Mn system and a thermodynamic description of the Al-Mg-Mn system. Int J Mater Res 98:855-871
25. Witusiewicz VT, Sommer F, Mittemeijer EJ (2004) Re-evaluation of the Fe-Mn phase diagram. J Phase Equilib Diff 25(4):346-354
26. Seierstein M (1998) Thermochemical database for light metal alloys, vol 1. European Commission, Luxembourg
27. Kattner UR, Burton BP (1993) Phase diagrams of binary iron alloys. ASM International, Materials Park
28. Jacobs MHG, Schmid-Fetzer R (2009) Phase behavior and thermodynamic properties in the system Fe-Al. Calphad 33(1):170-178
29. Kaufman L, Nesor H (1978) Coupled phase diagrams and thermochemical data for transition metal binary systems-V. Calphad 2(4):325-348
30. Mcalister AJ, Murray JL (1987) The (Al-Mn) aluminum-manganese system. J Phase Equilib Diff 8(5):438-447
31. Jansson Å (1992) A thermodynamic evaluation of the Al-Mn system. Metall Trans A 23(11):2953-2962
32. Kono H (1958) On the ferromagnetic phase in manganese-aluminum system. J Phys Soc Jpn 13(12):1444-1451
33. Chen LY, Li CH, Qiu AT et al (2010) Calculation of phase equilibria in Ti-Al-Mn ternary system involving a new ternary intermetallic compound. Intermetallics 18(11):2229-2237
34. Kaufman L (1978) Coupled phase diagrams and thermochemical data for transition metal binary systems-Ⅲ. Calphad 2(2):117-146
35. Huang W (1987) An assessment of the Fe-Mn system. Calphad 11(2):183-186
36. Byeong-Joo L, Dong L, Yung N (1989) A thermodynamic study on the Mn-C and Fe-Mn systems. Calphad 13(4):345-354
37. Stein F, Palm M (2007) Re-determination of transition temperatures in the Fe-Al system by differential thermal analysis. Int J Mater Res 98(7):580-588
38. Lee JR (1960) Liquidus-solidus relations in the system iron-aluminum. J Iron Steel Inst Met 194:222-224
39. Schuermann E, Kaiser HP (1980) Contribution to the melting equilibria of iron-aluminum and iron-phosphorous alloys. Arch Eisenhuettenwes 51:325-327
40. Inden G, Pepperhoff W (1990) Experimental study of the order:disorder transition in bcc Fe-Al alloys. Zeitschrift für Metallkunde 81(10):770-773
41. Dix EH, Fink WL, Willey LA (1933) Equilibrium relations in AlMn alloys of high purity Ⅱ. Trans AIME 104:335-352
42. Godecke T, Koster W (1971) A supplement to the constitution of the Al-Mn system. Z Metallkd 62:727-732
43. Koch AJJ, Hokkeling P, Steeg MGVD et al (1960) New material for permanent magnets on a base of Mn and Al. J Appl Phys 31:S75-S77
44. Koster W, Wachtel E (1960) Magnetic investigation of Al-Mn alloys containing more than 25at.% Mn. Z Metallkd 51:271-280
45. Kone H (1958) On the ferromagnetic phase in Mn-Al system. J Phys Soc Jpn 13:1444-1451
46. Liu XJ, Ohnuma I, Kalnuma R et al (1996) Phase equilibria in the Mn-rich portion of the binary system Mn-Al. J Alloy Compd 235:256-261
47. Murray JL, Mcalister AJ, Schaefer RJ et al (1987) Stable and metastable phase equilibria in the Al-Mn system. Metall Trans A 18A:385-392
48. Du Y, Jin ZP, Huang BY et al (2004) A thermodynamic description of the Al-Mn-Si system over the entire composition and temperature ranges. Metall Trans A 35(5):1613-1628
49. Weitzer F, Rogl P, Hayes FH (1996) Phase relations in the aluminium-rich part of the system:aluminium-iron-manganese. Deutsche Gesellshaft fur Materialkunde, Germany
50. Troiano AR, Mcguire FT (1943) A study of the iron-rich ironmanganese alloys. Trans ASM 31:340-359
51. Hellawell A, Hume-Rothery W (1957) The constitution of alloys of iron and manganese with transition elements of the first long period. Philos Trans R Soc Lond 249:417-459
52. Srivastava KK, Kirkadly JS (1982) The alpha-gamma phase boundary and the T₀ line for Fe-Mn alloys. Met Trans 13A:2113-2119
53. Serneels A, Davignon G, Niu X et al (1994) An overview of the research activities in the Al-Fe-Mn system. MTM-COST 507Ⅱ. European Commission, Luxembourg, pp 1-10
54. Weitzer F, Rogl P, Bohn M (1998) Definition of thermochemical and thermophysical properties to provide a database for the development of new light metal alloys. European Commission, Luxembourg
55. Davignon G, Verlinden B, Delaey L (1995) Experimental investigation of selected key compositions in order to determine the Al-Fe-Mn phase diagram. IWT-COST 507Ⅱ. European Commission, Luxembourg, pp 1-49
56. Schmatz DJ (1959) Formation of b-manganese-type structure in iron-aluminum-manganese alloys. Trans Met Soc AIME 215:112-114
57. Liu XJ, Hao SM, Sun RY (1993) Isotherrmal section at 1000℃ and 1 100℃ of Fe-Mn-Al phase diagram. Aata Metall Sin 6(7):94-98
58. Phragmen G (1950) On the phases occurring in alloys of aluminum with copper, magnesium, manganese, iron and silicon. J Inst Met 77:489-552
59. Denholm WT, Esdaile JD, Siviour NG (1987) The nature of the FeAl₃ liquid-(Fe, Mn)Al₆ reaction in the Al-Fe-Mn system. Metall Trans A 18A:393-397
60. Ursache M (1978) Studies of the possibilities of using some alloys of the Al-Mn-M system for the fabrication of permanent magnets. Bul Inst Politech Bucures Chim Met 40(3):105-112
61. Dinsdale AT (1991) SGTE data for pure elements. Calphad 15:317-425
62. Effenberg G, Ilyenko S (2005) Light metal systems. Part 2. Springer, Berlin
63. Sato K, Tanaka K, Inoue Y (1989) Determination of the a/c equilibrium in their on rich portion of the Fe-Mn-Al system. Science 29(9):788-792
64. Liu XJ, Kainuma R, Ohtani H et al (1996) Phase equilibria in the Mn-rich portion of the binary system Mn-Al. J Alloys Compd 235(2):256-261
65. Batalin GI, Bondarenko TP, Sudavtsova VS (1985) Enthalpies of mixing in the Fe-Mn-Al systems. Dopov Nat Akad Nauk Ukr 4:76-78