Molecular and crystal assembly inside the carbon nanotube: encapsulation and manufacturing approaches

  • Sergio Manzetti
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  • 1. Fjordforsk A.S., Institute of Science and Technology,
    6896 Fresvik, Norway  
    2.Van der Spoel Lab. Computational Systems and Biology,
    Biomedical Centre, University of Uppsala, P. O. Box 256,
    751 05 Uppsala, Sweden

Received date: 2013-04-30

  Online published: 2013-06-04

Abstract

Encapsulation of different guest-species such as molecules and ions inside carbon nanotubes (CNTs) has been reported in the literatures during the last 15 years and represents  an exciting development of nanoengineering of novel materials and composites. The reported nanocomposite materials show the semi-conducting properties with potential applications in nanosensors, nanounits and nanocircuits aswell as advanced energy transfer and storage properties, and encompassmanufacturing for novel nanowires, nanoelectronic devices with properties designed with optoelectronic, spintronic
and nanomagnetic qualities. This review reports on a wide range of encapsulation references with particular focus on single molecules, atomic chains, metal halides and polymers encapsulated inside CNTs. The encapsulationmethods and the chemical and physical qualities of these novel materials are
crucial for the future manufacturing of novel innovations in nanotechnology, and represent therefore the current state-ofthe-art of encapsulation methods in advanced manufacturing.

Cite this article

Sergio Manzetti . Molecular and crystal assembly inside the carbon nanotube: encapsulation and manufacturing approaches[J]. Advances in Manufacturing, 2013 , 1(3) : 198 -210 . DOI: DOI10.1007/s40436-013-0030-5

References

1. Guan L, Shi Z, Li M et al (2005) Ferrocene-filled single-walled carbon nanotubes. Carbon 43:2780–2785

2. Obergfell D, Meyer JC, Haluska M et al (2006) Transport and TEM on dysprosium metallofullerene peapods. Phys Status Solidif B 243:3430–3434

3. Del Carmen Gimenez-Lopez M, Chuvilin A, Kaiser U et al (2011) Functionalised endohedral fullerenes in single-walled carbon nanotubes. Chem Commun (Camb) 47:2116–2118

4. Del Carmen Gimenez-Lopez M, La Torre A, Fay MW et al (2013) Assembly and magnetic bistability of Mn3O4 nanoparticles encapsulated in hollow carbon nanofibers. Angew Chem Int Ed Engl 52:2051–2054

5. Faist J, Capasso F, Sirtori C et al (1995) Continuous wave operation of a vertical transition quantum cascade laser above T = 80 K. Appl Phys Lett 67:3057–3059

6. To´th G, Lent CS (2001) Quantum computing with quantum-dot cellular automata. Phys Rev A 63:052315

7. Lindner NH, Refael G, Galitski V (2011) Floquet topological insulator in semiconductor quantum wells. Nat Phys 7:490–495

8. Meunier V, Sumpter BG (2005) Amphoteric doping of carbon nanotubes by encapsulation of organic molecules: electronic properties and quantum conductance. J Chem Phys 123:24705

9. Dinadayalane TC, Gorb L, Simeon T et al (2007) Cumulativeinteraction triggers unusually high stabilization of linear hydrocarbon inside the single-walled carbon nanotube. Int J Quantum Chem 107:2204–2210

10. Smith BW, Monthoux M, Luzzi DE (1998) Encapsulated C60 in carbon nanotubes. Nature 396:323–324

11. Maniwa Y, Kumazawa Y, Saito Y et al (1999) Anomaly of X-ray diffraction profile in single-walled carbon nanotubes. Jpn J Appl Phys Lett 38:L668–L670

12. Takenobu T, Takano T, Shiraishi M et al (2003) Stable and controlled amphoteric doping by encapsulation of organic molecules inside carbon nanotubes. Nat Mater 2:683–688

13. Morgan DA, Sloan J, Green ML (2002) Direct imaging of o-carborane molecules within single walled carbon nanotubes. Chem Commun 20:2442–2443

14. Smith BW, Luzzi DE (2000) Formation mechanism of fullerene peapods and coaxial tubes: a path to large scale synthesis. Chem Phys Lett 321:169–174

15. Kiang CH, Choi JS, Tran TT et al (1999) Molecular nanowires of 1 nm diameter from capillary filling of single-walled carbon nanotubes. J Phys Chem B 103:7449–7451

16. Sloan J, Hammer J, Zwiefka-Sibley M et al (1998) The opening and filling of single walled carbon nanotubes (SWTs). Chem Commun 3:347–348

17. Sloan J, Dunin-Borkowski RE, Hutchison JL et al (2000) The size distribution, imaging and obstructing properties of C60 and higher fullerenes formed within arc-grown single walled carbon nanotubes. Chem Phys Lett 316:191–198
18. Zhang Y, Iijima S, Shi Z et al (1999) Defects in arc-dischargeproduced single-walled carbon nanotubes. Philos Mag Lett 79:473–479

19. Wang ZX, Ke XZ, Zhu ZY et al (2000) Carbon-atom chain formation in the core of nanotubes. Phys Rev B 61:R2472–R2474

20. Warner J, Ru¨mmeli MH, Bachmatiuk A et al (2010) Structural transformations of carbon chains inside nanotubes. Phys Rev B 81:155419

21. Nishide D, Dohi H, Wakabayashi T et al (2006) Single-wall carbon nanotubes encaging linear chain C10H2 polyyne molecules inside. Chem Phys Lett 428:356–360

22. Zhao X, Ando Y, Liu Y et al (2003) Carbon nanowire made of a long linear carbon chain inserted inside a multiwalled carbon nanotube. Phys Rev Lett 90:187401–187404

23. Sheng L, Jin A, Yu L et al (2012) A simple and universal method for fabricating linear carbon chains in multiwalled carbon nanotubes. Mater Lett 81:222–224

24. Koshino M, Tanaka T, Solin N et al (2007) Imaging of single organic molecules in motion. Science 316:853

25. Chamberlain TW, Biskupek J, Rance GA et al (2012) Size, structure, and helical twist of graphene nanoribbons controlled by confinement in carbon nanotubes. ACS Nano 6:3943–3953

26. Chuvilin A, Bichoutskaia E, Gimenez-Lopez MC et al (2011) Self-assembly of a sulfur-terminated graphene nanoribbon within a single-walled carbon nanotube. Nat Mater 10:687–692

27. Tang J, Huo Z, Brittman S et al (2011) Solution-processed coreshell nanowires for efficient photovoltaic cells. Nat Nanotechnol 6:568–572

28. Meyer RR, Sloan J, Dunin-Borkowski RE et al (2000) Discrete atom imaging of one-dimensional crystals formed within singlewalled carbon nanotubes. Science 289:1324–1327

29. Lee J, Kim H, Kahng SJ et al (2002) Bandgap modulation of carbon nanotubes by encapsulated metallofullerenes. Nature 415: 1005–1008

30. Sloan J, Kirkland AI, Hutchison JL et al (2002) Integral atomic layer architectures of 1D crystals inserted into single walled carbon nanotubes. Chem Commun: 1319–1332. doi:10.1039/B200537A

31. Bendall JS, Ilie A, Welland ME et al (2006) Thermal stability and reactivity of metal halide filled single-walled carbon nanotubes. J Phys Chem B 110:6569–6573

32. Zhou J, Song H, Chen X et al (2010) Diffusion of metal in a confined nanospace of carbon nanotubes induced by air oxidation. J Am Chem Soc 132:11402–11405

33. La Torre A, Del Carmen Gimenez-Lopez M, Fay MW et al (2012) Assembly, growth, and catalytic activity of gold nanoparticles in hollow carbon nanofibers. ACS Nano 6:2000–2007

34. Sloan JM, Wright D, Bailey S et al (1999) Capillarity and silver nanowire formation observed in single walled carbon nanotubes. Chem Commun: 699–700. doi:10.1039/A901572H

35. Rothschild A, Sloan J, Tenne R (2000) Growth of WS2 nanotubes phases. J Am Chem Soc 122:5169–5179

36. Xu C, Sloan J, Brown G et al (2000) 1D lanthanide halide crystals inserted into single-walled carbon nanotubes. Chem Commun 24:2427–2428

37. Del Carmen Gimenez-Lopez M, Moro F, La Torre A et al (2011) Encapsulation of single-molecule magnets in carbon nanotubes. Nat Commun 2:407

38. Guan L, Suenaga K, Shi Z et al (2007) Polymorphic structures of iodine and their phase transition in confined nanospace. Nano Lett 7:1532–1535

39. Philip E, Sloan J, Kirkland AI et al (2003) An encapsulated helical one-dimensional cobalt iodide nanostructure. Nat Mater 2:788–791

40. Ugarte D, Chatelain A, de Heer WA (1996) Nanocapillarity and chemistry in carbon. Science 274:1897–1899
41. Gubin SP, Koksharov YA (2002) Preparation, structure, and properties of magnetic materials based on co-containing nanoparticles. Inorg Mater 38:1085–1099

42. Liu Z, Dai X, Xu J et al (2004) Encapsulation of polystyrene within carbon nanotubes with the aid of supercritical CO2. Carbon 42:458–460

43. Steinmetz J, Kwon S, Lee HJ et al (2006) Polymerization of conducting polymers inside carbon nanotubes. Chem Phys Lett 431:139–144

44. Bazilevsky AV, Sun K, Yarin AL et al (2007) Selective intercalation of polymers in carbon nanotubes. Langmuir 23: 7451–7455

45. Britz DA, Khlobystov AN, Porfyrakis K et al (2005) Chemical reactions inside single-walled carbon nano test-tubes. Chem Commun 107:37–39

46. Ito T, Shirakawa H, Ikeda S (1975) Thermal cis–trans isomerization and decomposition of polyacetylene. J Polym Sci 12:1943–1950

47. Chiang CK, Fincher CB, Park YW et al (1977) Electrical conductivity in doped polyacetylene. Phys Rev Lett 39:1098–1101

48. Chiang CK, Druy MA, Gau SC et al (1978) Synthesis of highly conducting films of derivatives of polyacetylene, (CH)x. J Am Chem Soc 100:1013–1015

49. Shirakawa H, Louis EJ, MacDiarmid AG et al (1977) Synthesis of electrically conducting organic polymers: halogen derivatives of polyacetylene, (CH)x. J Am Chem Soc: 578

50. Ravve A (2012) Principles of polymer chemistry. Springer, New York

51. McCormick CL, Kirkland SE, YorkAW(2006) Synthetic routes to stimuli–responsive micelles, vesicles, and surfaces via controlled/living radical polymerization. J Macromol Sci C 46:421–443

52. Oh JK, Drumright R, Siegwart DJ et al (2008) The development of microgels/nanogels for drug delivery applications. Prog Polym Sci 33:448–477

53. Matyjaszewski K, Tsarevsky NV (2009) Nanostructured functional materials prepared by atom transfer radical polymerization. Nat Chem 1:276–288

54. Khlobystov AN (2011) Carbon nanotubes: from nano test tube to nano-reactor. ACS Nano 5:9306–9312

55. Chamberlain TW, Gimenez-Lopez MdC, Khlobystov AN (2010) Carbon nanotubes as containers. In: Carbon nanotubes and related structures. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, pp 349–384

56. Shi XQ, Dai ZX, Zhong GH et al (2007) Spin-polarized transport  in carbon nanowires inside semiconducting carbon nanotubes. J Phys Chem C 111:10130–10134

57. Tran-Duc T, Thamwattana N (2011) Modeling encapsulation of acetylene molecules into carbon nanotubes. J Phys 23:225302

58. Lee SU, Belosludov RV, Mizuseki H et al (2011) Electron transport characteristics of organic molecule encapsulated carbon nanotubes. Nanoscale 3:1773–1779

59. Ilie A, Bendall JS, Nagaoka K et al (2011) Encapsulated inorganic nanostructures: a route to sizable modulated, noncovalent, on-tube potentials in carbon nanotubes. ACS Nano 5:2559–2569

60. Kuwahara R, Kudo Y, Morisato T et al (2011) Encapsulation of carbon chain molecules in single-walled carbon nanotubes. J Phys Chem A 115:5147–5156

61. McIntosh GC, Tomanek D, Park YW (2003) Energetics and  electronic structure of a polyacetylene chain contained in a carbon nanotube. Phys Rev B 67:125419

62. Kim G, Kim Y, Ihm J (2005) Encapsulation and polymerization of acetylene molecules inside a carbon nanotube. Chem Phys Lett 415:279

63. BeckeA(1998) Density-functional exchange-energy approximation with correct asymptotic behavior. Phys Rev A 38:3098–3100
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