Application of thermodynamics in designing of advanced automotive steels
Received date: 2016-07-25
Revised date: 2016-09-28
Online published: 2016-12-25
Supported by
This work is financially supported by the National Key Basic Research Development Project of China (Grant No. 2010CB630802);the National Natural Science Foundation of China (Grant Nos.50934011 and 50971137) and Shanghai University.
Advanced automotive steels were designed with alloy concept and thermodynamics. Several phases were taken for the designing of transformation induced plasticity(TRIP) steels in accordance with the practical metallurgy process. Al was firstly chosen to substitute Si for improving galvanizing property, afterwards P was proved to be another alternative of Si by thermodynamic calculation and kinetic estimation. Thermodynamic investigation in the third phase revealed the effective function of Al to increase carbon solubility in austenite as well as TRIP effect of steel. Stack fault energy was calculated, in combination with heat treatment and microstructure measurement, which led to a successful composition designing of twin induced plasticity (TWIP) steel.
Key words: Thermodynamics; Phase diagram; Materials designing; Advanced steel
Lin Li , Hu Jiang . Application of thermodynamics in designing of advanced automotive steels[J]. Advances in Manufacturing, 2016 , 4(4) : 340 -347 . DOI: 10.1007/s40436-016-0156-3
1. Matsumumura O, Sakuma Y, Takechi A(1987) Enhancement of elongation by retained austenite in intercritical annealed 0.4 C-1.5 Si-0.8 Mn steel. Trans. ISIJ 27:570
2. Li Lin, De Cooman BC, Wollants P et al(2004) Effect of aluminum and silicon on transformation induced plasticity of the TRIP steel. J Mater Sci Technol 20(2):135-138
3. Li L, Liu R, Shi W et al(2009) Development of a new type TRIP steel with good weldability and galvanizing property. In:Proceedings of international symposium automobile steel, Dalian, China, 2009, pp 332-336
4. Guttmann M, Mclean D(1979) Grain boundary segregation in multicomponent systems. In:Johnson WC, Blakely JM(eds) Interfacial segregation. ASM, Metals Park, pp 261-348
5. Hillert M, Staffansson LI(1970) Regular-solution model for stoichiometric phases and ionic melts. Acta Chem Scand 24:3618
6. Li L, Delaey L, Wollants P et al(1993) Thermodynamic analysis of the segregation of multicomponent steels. J Chim Phys 90:305-311
7. Li L, Delaey L, Wollants P et al(1996) Thermodynamic calculation of segregation in multicomponent steels. J Mater Sci Technol 12(3):238-240
8. Guttmann M, Dumoulin Ph, Wayman M(1982) The thermodynamics of interactive co-segregation of phosphorus and alloying elements in iron and temper-brittle steels. Metall Trans 13A:1693-1711
9. Li L(2010) Microstructure and property control of advanced high strength automotive steel. In:Weng YQ, Dong H, Gan Y(eds) Metalluygical. Industry Press, Beijing, p 265
10. Mclean D(1957) Grain boundaries in metals. Clarendon Press, Oxford
11. Sundman B, Jansson B, Andersson J(1985) The thermo-calc databank system. Calphad 9(2):153-190
12. Li L, Huang SG, Wang L et al(2009) Thermodynamic reassessment of the Fe-Al-C system based on the Fe-rich experimental data. Front Mater Sci China 3(1):33-37
13. Redlich O, Kister AT(1948) Algebraic representation of thermodynamic properties and the classification of solutions. Ind Eng Chem 40:345-348
14. Sundman B, Ågren J(1981) A regular solution model for phases with several components and sublattices, suitable for computer applications. J Phys Chem Solids 42(4):297-301
15. Kumar KCH, Raghavan V(1991) a thermodynamic analysis of the Al-C-Fe system. J Phase Equilib 12(3):275-286
16. Gustafson P(1985) A thermodynamic evaluation of the Fe-C system. Scand J Metall 14:259
17. Matlock DK, Speer JG(2009) Third generation of AHSS, microstructure design concepts. In:Haldar A, Suwas S, Bhattacharjee D(eds) Microstructure and texture in steels. Springer, New York, pp 185-205
18. Li L, Gao Y, Shi W et al(2011) Martensite transformation in high Mn steels. HMnS2011, Soeal, Korea, p A19
19. Olson GB, Cohen M(1976) A general mechanism of martensitic nucleation:Part Ⅱ. FCC→BCC and other martensitic transformations. Metall Trans A 7A:1905-1914
20. Allain S, Chateau JP, Bouaziz O et al(2004) Correlations between the calculated stacking fault energy and the plasticity mechanisms in Fe-Mn-C alloys. Mater Sci Eng A 387-389:158-162
21. Dumaya A, Chateau JP, Allain S et al(2008) Application of thermodynamics and kinetics in materials engineering. Mater Sci Eng A 483-484:184-187
22. Inden G(1977) Determination of chemical and magnetic interchange and magnetic interchange energies in BCC alloys. Metallkde Z 68:529-534
23. Hillert M, Jarl M(1978) A model for alloying in ferromagnetic metals. Calphad 2:227-238
24. Dinsdale AT(1991) SGTE data for pure elements. Calphad 15:317-425
/
| 〈 |
|
〉 |